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Adducts of methyl β,β-bis(trifluoromethyl)acrylate with nucleophiles and allylic rearrangement during their dehydrofluorination

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A number of adducts of methyl β,β-bis(trifluoromethyl)acrylate with various nucleophiles were synthesized. The boundaries of the allylic rearrangement of 2-substituted 3-trifluoromethyl-4,4-difluoro-3-butenoates, obtained by dehydrofluorination of the cited adducts, were investigated.

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Literature cited

  1. I. V. Solodin, A. V. Eremeev, É. É. Liepin'sh, and R. G. Kostyanovskii, Khim. Geterotsikl. Soedin., No. 4, 505 (1985).

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  2. I. L. Knunyants and Yu. A. Cheburkov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, No. 12, 2162 (1960).

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Authors and Affiliations

  1. Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga

    I. V. Solodin, A. V. Eremeev, I. I. Chervin & R. G. Kostyanovskii

  2. Institute of Chemical Physics, Academy of Sciences of the USSR, 117977, Moscow

    I. V. Solodin, A. V. Eremeev, I. I. Chervin & R. G. Kostyanovskii

Authors
  1. I. V. Solodin
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  2. A. V. Eremeev
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  3. I. I. Chervin
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  4. R. G. Kostyanovskii
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1359–1362, October, 1985.

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Solodin, I.V., Eremeev, A.V., Chervin, I.I. et al. Adducts of methyl β,β-bis(trifluoromethyl)acrylate with nucleophiles and allylic rearrangement during their dehydrofluorination. Chem Heterocycl Compd 21, 1113–1116 (1985). https://doi.org/10.1007/BF00515249

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  • DOI: https://doi.org/10.1007/BF00515249

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