Chemistry of Heterocyclic Compounds

, Volume 20, Issue 4, pp 416–421 | Cite as

Diazo carbonyl derivatives of heterocycles. 3. Alternative 1,3-dipolar addition to azidoalkyl α-diazo ketones and synthesis of five-membered heterocycles based on them

  • V. G. Kartsev
  • T. S. Pokidova
  • A. S. Nabatov
  • A. V. Dovgilevich


It is shown that the cycloaddition of dimethylacetylenedicarboxylate and N-phenylmaleinimide to azidoalkyl diazomethyl ketones leads to the corresponding 1,2,3-triazole and 2-pyrazoline derivatives. The electronic structure of one of the bisdipoles was determined.


Organic Chemistry Carbonyl Ketone Dimethylacetylenedicarboxylate Diazomethyl 
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Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • V. G. Kartsev
    • 1
  • T. S. Pokidova
    • 1
  • A. S. Nabatov
    • 1
  • A. V. Dovgilevich
    • 1
  1. 1.Branch of the Institute of Chemical PhysicsAcademy of Sciences of the USSRChernogolovka

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