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Effect of the inclusion of a cyclic fragment in the chromophore on the properties of a spiropyran-merocyanine system

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The corresponding merocyanines, which do not display a tendency to form spiropyran structures, are formed in the condensation of 1,3,3-trimethyl-2-methyleneindoline with 5-methyl-2-furoylacetaldehyde, 2-formylcyclohexanone, or 2-formyl-1-tetralone. Spiran compounds in which the spiropyran—merocyanine equilibrium is shifted markedly to favor the closed form are formed when 4a,9-dimethyl-2,3,4,4a-tetrahydrocarbazone — the cyclic analog of the Fischer base — is used in the reaction with salicylaldehydes and benzoylacetaldehydes.

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Authors and Affiliations

  1. Scientific-Research Institute of Organic Intermediates and Dyes, 103787, Moscow

    M. A. Gal'bershtam, A. P. Sidorov, N. M. Przhiyalgovskaya, Yu. P. Strokach, V. A. Barachevskii, I. V. Manakova & N. N. Suvorov

  2. D. Mendeleev Moscow Institute of Chemical Technology, 125047, Moscow

    M. A. Gal'bershtam, A. P. Sidorov, N. M. Przhiyalgovskaya, Yu. P. Strokach, V. A. Barachevskii, I. V. Manakova & N. N. Suvorov

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  1. M. A. Gal'bershtam
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  2. A. P. Sidorov
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  3. N. M. Przhiyalgovskaya
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  4. Yu. P. Strokach
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  5. V. A. Barachevskii
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  6. I. V. Manakova
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  7. N. N. Suvorov
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1205–1210, September, 1982.

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Gal'bershtam, M.A., Sidorov, A.P., Przhiyalgovskaya, N.M. et al. Effect of the inclusion of a cyclic fragment in the chromophore on the properties of a spiropyran-merocyanine system. Chem Heterocycl Compd 18, 923–928 (1982). https://doi.org/10.1007/BF00513433

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  • DOI: https://doi.org/10.1007/BF00513433

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