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Porphyrins. 14. Synthesis and properties of 1-substituted derivatives of 5,10,15,20-tetraphenylporphyrin

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The Vilsmeier formylatlon of the cobalt complex of 5,10,15,20-tetraphenylporphyrin was realized, and its intermediate salt with the dimethylformamide-POC13 complex was isolated; demetallation of the latter gave 1-formyl-5,10,15,20-tetraphenylporphyrin. Formyltetraphenylporphyrin oxime and its 0-acetyl derivative and 1-cyano-5,10,15, 20-tetraphenylporphyrin were synthesized. The Wittig reaction with formylporphyrin and its copper and cobalt complexes with methoxycarbonylmethinyltriphenylphosphorane and diethylamidocarbonylmethinylhexamethyltriamidophosphorane was realized, and conditions that affect the ratios of the Z and E isomers of the acrylic derivatives obtained were studied.

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Authors and Affiliations

  1. Institute of Biophysics, Ministry of Public Health of the USSR, 123182, Moscow

    G. V. Ponomarev & G. B. Maravin

Authors
  1. G. V. Ponomarev
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  2. G. B. Maravin
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Additional information

See [1] for Communication 13.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 59–64, January, 1982.

The authors sincerely thank L. B. Lazukova and A. M. Shul'ge for recording the PMR spectra, V. P. Suboch for recording the mass spectra, and I. I. Mizrakhfor providing us with a sample of phosphorane B.

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Ponomarev, G.V., Maravin, G.B. Porphyrins. 14. Synthesis and properties of 1-substituted derivatives of 5,10,15,20-tetraphenylporphyrin. Chem Heterocycl Compd 18, 50–55 (1982). https://doi.org/10.1007/BF00513288

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  • DOI: https://doi.org/10.1007/BF00513288

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