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Free-radical pyridylethylation of arylalkanes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

2-(3-Arylpropyl)pyridines were synthesized in 30–54% yields by the free-radical addition of toluene, o-, m-, and p-xylenes, and mesitylene to 2-vinylpyridine at 250–350 °C. The products of rearrangement of the intermediate adduct radical with 1,3-H migration were isolated and identified.

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Authors and Affiliations

  1. Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, 700170, Tashkent

    G. G. Galust'yan, E. A. Il'yasov & Ch. Sh. Kadyrov

Authors
  1. G. G. Galust'yan
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  2. E. A. Il'yasov
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  3. Ch. Sh. Kadyrov
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 377–380, March, 1983.

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Galust'yan, G.G., Il'yasov, E.A. & Kadyrov, C.S. Free-radical pyridylethylation of arylalkanes. Chem Heterocycl Compd 19, 307–310 (1983). https://doi.org/10.1007/BF00513267

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  • DOI: https://doi.org/10.1007/BF00513267

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