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Conformational study of trans-(+)-(9S,10S)-decahydro-4-quinolone and its n-substituted derivatives

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Abstract

The spectropolarometric study of trans-(+)-(9S,10S)-decahydro-4-quinolone indicates the existence of invertomers with respect to the nitrogen atom, conformers formed during rotation of the substituent attached to the nitrogen atom about the C-N bond for trans-(9S,10S)-N-(α-phenylethyl)decahydro-4-quinolone, and conformers formed through conversion of the two-ring system for cis-(9R,10S)-N-(α-phenylethyl)decahydro-4-quinolone.

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Literature cited

  1. V. M. Potapov, G. V. Grishina, E. A. Golov, P. V. Terent'ev, and R. Khertsshu, Khim. Geterotsikl. Soedin., No. 7, 953 (1976).

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    V. M. Potapov, G. V. Grishina & E. A. Golov

Authors
  1. V. M. Potapov
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  2. G. V. Grishina
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  3. E. A. Golov
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Additional information

Communication XXXVIII from the series “Stereochemical Studies”; see [1] for communication XXXVII.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1093–1097, August, 1976.

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Potapov, V.M., Grishina, G.V. & Golov, E.A. Conformational study of trans-(+)-(9S,10S)-decahydro-4-quinolone and its n-substituted derivatives. Chem Heterocycl Compd 12, 902–906 (1976). https://doi.org/10.1007/BF00510112

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  • DOI: https://doi.org/10.1007/BF00510112

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