Skip to main content
SpringerLink
Log in

Mass spectra of substituted piperidines

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The mass spectra of piperidines and N-methylpiperidines with various functional groups attached to the heteroring carbon atoms were studied. The mechanisms of the formation and fragmentation of the amine fragments with various structures and specific hydrogen and skeletal rearrangements are discussed. It is shown that the sequence of cleavage of the heteroring bonds depends on the properties of the substituents and their positions in the ring.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. I. Ermakov, Zh. K. Torosyan, and Yu. N. Sheinker, Khim. Geterotsikl. Soedin., No. 4, 507 (1979).

    Google Scholar 

  2. A. I. Ermakov, Yu. N. Sheinker, Zh. K. Torosyan, and V. A. Zamureenko, Khim. Geterotsikl. Soedin., No. 12, 1647 (1975).

    Google Scholar 

  3. T. F. Vlasova, K. F. Turchin, A. A. Mel'nikova, E. S. Nikitskaya, and Yu. N. Sheinker, Khim. Prir. Soedin., No. 5, 591 (1970).

    Google Scholar 

  4. V. I. Mamonov, G. G. Dvoryantseva, É. V. Sysoeva, and B. V. Unkovskii, Zh. Org. Khim., 6, 1087 (1970).

    Google Scholar 

  5. R. G. Kostyanovskii, A. P. Pleshkova, V. N. Voznesenskii, A. V. Prosyanik, G. K. Kadorkina, and V. F. Rudchenko, Khim. Geterotsikl. Soedin., No. 5, 624 (1977).

    Google Scholar 

  6. H. Budzikiewicz, C. Djerassi, and D. Williams, Interpretation of the Mass Spectra of Organic Compounds, Holden-Day, San Francisco (1964).

    Google Scholar 

  7. V. V. Takhistov, Practical Mass Spectrometry of Organic Compounds [in Russian], Izd. Leningrad. Univ., Leningrad (1977), p. 123.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. S. Ordzhonikidze All-Union Scientific-Research Institute of Pharmaceutical Chemistry, 119021, Moscow

    A. I. Ermakov & Yu. N. Sheinker

Authors
  1. A. I. Ermakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. N. Sheinker
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Communication 9 in the series “Application of mass spectrometry in structural and stereochemical investigations.” See [1] for Communication 8.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 65–71, January, 1981.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ermakov, A.I., Sheinker, Y.N. Mass spectra of substituted piperidines. Chem Heterocycl Compd 17, 52–57 (1981). https://doi.org/10.1007/BF00507092

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00507092

Keywords

Search

Navigation