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Investigation of the pathways of thermal fragmentation of thiacarbocyanine dyes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The pathways of the thermal transformations of thiacarbocyanines with various alkyl groups attached to the ring nitrogen atoms of the heteroresidues, of 3,3′-diethylthiacarbocyanine with various anions, and its anhydro base were investigated. The results of the studies are compared with the results of quantumchemical calculations of the labilities of the bonds in these compounds by the Pariser-Parr-Pople method.

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Literature cited

  1. L. G. S. Brooker and R. H. Sprague, J. Am. Chem. Soc., 62, 1116 (1940).

    Google Scholar 

  2. K. K. Zhigulev, F. L. Kolodkin, R. D. Raikhina, M. A. Al'perovich, and I. I. Levkoev, Dokl. Akad. Nauk SSSR, 215, 347 (1974).

    Google Scholar 

  3. M. A. Al'perovich, R. D. Raikhina, V. G. Khesin, T. D. Medvedeva, and I. I. Levkoev, Dokl. Akad. Nauk SSSR, 227, 118 (1976).

    Google Scholar 

  4. P. I. Abramenko and V. A. Kosobutskii, Khim. Geterotsikl. Soedin., No. 5, 626 (1978).

    Google Scholar 

  5. M. A. Al'perovich, V. G. Khesin, R. D. Raikhina, and T. D. Medvedeva, Khim. Geterotsikl. Soedin., No. 12, 1620 (1981).

    Google Scholar 

  6. M. A. Al'perovich, F. L. Kolodkin, V. G. Khesin, R. D. Raikhina, and T. D. Medvedeva, Khim. Geterotsikl. Soedin., No. 10, 1358 (1979).

    Google Scholar 

  7. N. Mataga and K. Nishimoto, Zeitschr. Phys. Chem., 136, 140 (1957).

    Google Scholar 

  8. K. Nishimoto, Theor. Chim. Acta, 7, 207 (1967).

    Google Scholar 

  9. K. Nishimoto and L. S. Forster, Theor. Chim. Acta, 4, 115 (1965).

    Google Scholar 

  10. V. A. Kosobutskii, G. I. Kagan, V. K. Belyakov, and O. G. Tarakanov, Zh. Struk. Khim., 12, 822 (1971).

    Google Scholar 

  11. J. Hinze and H. H. Jaffe, J. Chem. Phys., 67, 1501 (1963).

    Google Scholar 

  12. P. Pariser and R. G. Parr, J. Chem. Phys., 21, 466, 767 (1953).

    Google Scholar 

  13. V. I. Minkin, B. Ya. Simkin, and L. P. Olekhnovich, Int. J. Sulfur Chem., 3A, 249 (1973).

    Google Scholar 

  14. M. J. S. Dewar and T. Morita, J. Am. Chem. Soc., 91, 796 (1969).

    Google Scholar 

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1626–1630, December, 1981.

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Khesin, V.G., Al'perovich, M.A. & Abramenko, P.I. Investigation of the pathways of thermal fragmentation of thiacarbocyanine dyes. Chem Heterocycl Compd 17, 1187–1192 (1981). https://doi.org/10.1007/BF00506990

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  • DOI: https://doi.org/10.1007/BF00506990

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