Abstract
The reaction of N-acetyl derivatives of N,N′-trimethylene- and N,N′-tetramethylene-o-phenylenediamines with ethylene oxide gave the corresponding N-(β-hydroxyethyl)-N′-acetyl derivatives, the cyclization of which in refluxing hydrobromic acid leads to benzo[f]-1,5-diazabicyclo[3.2.2]nonene and benzo[g]-1,6-diazabicyclo[4.2.2.]decene.
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See [1] for Communication 5.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1538–1542, November, 1981.
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Shishkin, G.V., Gall, A.A. & Zloba, G.A. Diazabicycloalkanes with nitrogen atoms in the nodal positions. 6. Synthesis and some properties of benzo[f]-1,5-diazabicyclo[3.2.2]nonene and benzo[g]-1,6-diazabicyclo[4.2.2]decene. Chem Heterocycl Compd 17, 1125–1128 (1981). https://doi.org/10.1007/BF00506465
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DOI: https://doi.org/10.1007/BF00506465