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Saturated nitrogen-containing heterocycles. 9. Synthesis and study of optically active pyrrolidinylalkanols and their tartrates

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Optically active 3-(5-methyl-2-pyrrolidinyl)-1-propanols and their tartrates were synthesized. The stereochemical structures of the latter were established by x-ray diffraction analysis and PMR and IR spectroscopy. The absolute configuration was determined for (−)-cis-3-(1,5-dimethyl-2-pyrrolidinyl)-1-propanol (+)-bitartrate dihydrate, and the conformational and structural peculiarities of the pyrrolidinium cation and the tartrate anion were studied.

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Authors and Affiliations

  1. N. G. Chernyshevskii Saratov State University, 410601, Saratov

    I. N. Klochkova, S. A. Lazarev, V. G. Andrianov, Yu. T. Strukhkov, G. K. Kravtsova & M. V. Noritsina

  2. N. I. Vavilov Saratov Agricultural Institute, 410600, Saratov

    I. N. Klochkova, S. A. Lazarev, V. G. Andrianov, Yu. T. Strukhkov, G. K. Kravtsova & M. V. Noritsina

  3. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, 117813, Moscow

    I. N. Klochkova, S. A. Lazarev, V. G. Andrianov, Yu. T. Strukhkov, G. K. Kravtsova & M. V. Noritsina

Authors
  1. I. N. Klochkova
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  2. S. A. Lazarev
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  3. V. G. Andrianov
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  4. Yu. T. Strukhkov
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  5. G. K. Kravtsova
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  6. M. V. Noritsina
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Additional information

See [1] for communication 8.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 222–225, February, 1983.

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Klochkova, I.N., Lazarev, S.A., Andrianov, V.G. et al. Saturated nitrogen-containing heterocycles. 9. Synthesis and study of optically active pyrrolidinylalkanols and their tartrates. Chem Heterocycl Compd 19, 180–183 (1983). https://doi.org/10.1007/BF00506431

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  • DOI: https://doi.org/10.1007/BF00506431

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