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Chemistry of Heterocyclic Compounds

, Volume 19, Issue 2, pp 180–183 | Cite as

Saturated nitrogen-containing heterocycles. 9. Synthesis and study of optically active pyrrolidinylalkanols and their tartrates

  • I. N. Klochkova
  • S. A. Lazarev
  • V. G. Andrianov
  • Yu. T. Strukhkov
  • G. K. Kravtsova
  • M. V. Noritsina
Article
  • 25 Downloads

Abstract

Optically active 3-(5-methyl-2-pyrrolidinyl)-1-propanols and their tartrates were synthesized. The stereochemical structures of the latter were established by x-ray diffraction analysis and PMR and IR spectroscopy. The absolute configuration was determined for (−)-cis-3-(1,5-dimethyl-2-pyrrolidinyl)-1-propanol (+)-bitartrate dihydrate, and the conformational and structural peculiarities of the pyrrolidinium cation and the tartrate anion were studied.

Keywords

Spectroscopy Organic Chemistry Diffraction Analysis Propanol Tartrate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • I. N. Klochkova
    • 1
    • 2
    • 3
  • S. A. Lazarev
    • 1
    • 2
    • 3
  • V. G. Andrianov
    • 1
    • 2
    • 3
  • Yu. T. Strukhkov
    • 1
    • 2
    • 3
  • G. K. Kravtsova
    • 1
    • 2
    • 3
  • M. V. Noritsina
    • 1
    • 2
    • 3
  1. 1.N. G. Chernyshevskii Saratov State UniversitySaratov
  2. 2.N. I. Vavilov Saratov Agricultural InstituteSaratov
  3. 3.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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