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Chemistry of Heterocyclic Compounds

, Volume 19, Issue 2, pp 174–177 | Cite as

Research on the chemistry of heterocyclic quinoneimines. Reaction of 3-phenothiazinone with alkoxides

  • G. B. Afanas'eva
  • V. I. Vysokov
  • T. K. Pashkevich
  • O. N. Chupakhin
Article
  • 34 Downloads

Abstract

Nucleophilic substitution of hydrogen to give 1- and 2-mono- and 1,7-dialkoxy-3-phenothiazinones, as well as a mixture of dimers, when 3-phenothiazinone is treated with alkali metal alkoxides. The effect of the nature of the alcohol, the alkali metal cation, and the solvent on the reaction was investigated.

Keywords

Hydrogen Alcohol Organic Chemistry Alkali Metal Metal Cation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    A. Selman, in: Cancer Chemotherapy Reports, Vol. 58, Part 1, No. 1 (1974), p. 1.Google Scholar
  2. 2.
    Houben-Weyl, Methoden der Organischen Chemie, Vol. VII/3a Chinone, Part 1, Georg Thieme Verlag, Stuttgart (1977), p. 286.Google Scholar
  3. 3.
    F. Farina and J. Valderrama, Synthesis, No. 3, 315 (1971).Google Scholar
  4. 4.
    H. Aschenbach and J. Worth, Chem. Ber., 110, 12 (1977).Google Scholar
  5. 5.
    Jain, K. Surendra, and R. L. Mital, Indian J. Chem., 12, 780 (1974).Google Scholar
  6. 6.
    Y. Tsujino, K. Nashikido, and T. Naito, Nippon Kagaku Zasshi, 91, 1080 (1970); Chem. Abstr., 74, 125598 (1971).Google Scholar
  7. 7.
    M. V. Diudea, Rev. Roum. Chim., 26, 725 (1981).Google Scholar
  8. 8.
    B. J. Herdd, M. Celina, B. L. R. Lazana, and H. M. Noviac, Tetrahedron, 33, 517 (1977).Google Scholar
  9. 9.
    C. Bodea and I. Silberg, Rev. Chim., 7, 683 (1962).Google Scholar
  10. 10.
    T. S. Viktorova, Author's Abstract of Master's Dissertation, Sverdlovsk (1976).Google Scholar
  11. 11.
    T. K. Pashkevich, G. B. Afanas'eva, I. Ya. Postovskii, and K. I. Pashkevich, Khim. Geterotsikl. Soedin., No. 3, 353 (1975).Google Scholar

Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • G. B. Afanas'eva
    • 1
  • V. I. Vysokov
    • 1
  • T. K. Pashkevich
    • 1
  • O. N. Chupakhin
    • 1
  1. 1.S. M. Kirov Ural Polytechnic InstituteSverdlovsk

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