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Synthesis and properties of sym-triazine derivatives. 3. alkoxylation of 2-alkyl-4,6-bis(trichloromethyl)-sym-triazines containing higher alkyl radicals

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Nucleophilic substitution reactions of trichloromethyl groups in 2-alkyl-4,6-bis-(trichloromethyl)-sym-triazines by alkoxy radicals were studied. It was shown that in the presence of sodium alcoholates, two CCl3 groups are replaced, and the corresponding 2,4-dialkoxy-6-alkyl-sym-triazines are formed. The products of partial replacement, 2-alkoxy-4-trichloromethyl-6-alkyl-sym-triazines, were synthesized by heating the initial sym-triazines with alcohols in the presence of tertiary amines.

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Literature cited

  1. E. Kober, J. Org. Chem., 25, 1728 (1960).

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  2. Ammar Dibi, Candidate Chemical Sciences Dissertation, the Moscow Institute of Petrochemical and Gas Industry, Moscow (1983).

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  3. P. A. Perov, A. T. Gerasimova, P. A. Kudryashov, and N. A. Sokova, Izv. Vuzov. Khim. i Khim. Tekhnol., 25, 1196 (1982).

    Google Scholar 

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Authors and Affiliations

  1. I. M. Gubkin Moscow Institute of Petrochemical and Gas Industry, 117917, Moscow

    V. I. Kelarev, Ammar Dibi & A. F. Lunin

Authors
  1. V. I. Kelarev
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  2. Ammar Dibi
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  3. A. F. Lunin
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1674–1677, December, 1984.

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Kelarev, V.I., Dibi, A. & Lunin, A.F. Synthesis and properties of sym-triazine derivatives. 3. alkoxylation of 2-alkyl-4,6-bis(trichloromethyl)-sym-triazines containing higher alkyl radicals. Chem Heterocycl Compd 20, 1380–1384 (1984). https://doi.org/10.1007/BF00505964

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  • DOI: https://doi.org/10.1007/BF00505964

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