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Synthesis and structure of derivatives of 7-oxo-4,5,6,7-tetrahydrobenzo[b]-thiophene and 7-hydroxybenzo[b]thiophene

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The oxidation of 2-acylamino-3-ethoxycarbonyl-4,5,6,7-tetrahydrobenzo[b]thiophenes gave the corresponding 7-oxotetrahydrobenzo[b]thiophenes and some of the transformations of these compounds were studied. These compounds were used for the synthesis of 3-ethoxycarbonyl-6-bromo-7-hydroxybenzo[b]thiophene. The structures of the compounds prepared were established by chemical and spectral methods.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1626–1629, December, 1984.

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Kharizomenova, I.A., Kapustina, M.V., Grinev, A.N. et al. Synthesis and structure of derivatives of 7-oxo-4,5,6,7-tetrahydrobenzo[b]-thiophene and 7-hydroxybenzo[b]thiophene. Chem Heterocycl Compd 20, 1339–1342 (1984). https://doi.org/10.1007/BF00505954

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  • DOI: https://doi.org/10.1007/BF00505954

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