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Pyrido[2,3-c]furoxan as a probable intermediate in the reaction of 2-nitro-3-azidopyridine with amines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Two parallel reactions, viz., cyclization of 2-nitro-3-azidopyridine to pyrido-[2,3-c]furoxan, which is aminated in the 6 position of the pyridine ring with opening of the furoxan ring, and reduction of the azido group to form 2-nitro-3-aminopyridine, occur in the reaction of 2-nitro-3-azidopyridine with amines. It was established that pyrido[2,3-c]furoxan reacts with amines in aqueous media in the 1-oxide form.

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Literature cited

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Deceased.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 654–657, May, 1981.

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Kotovskaya, S.K., Mokrushina, G.A., Postovskii, I.Y. et al. Pyrido[2,3-c]furoxan as a probable intermediate in the reaction of 2-nitro-3-azidopyridine with amines. Chem Heterocycl Compd 17, 480–483 (1981). https://doi.org/10.1007/BF00505694

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  • DOI: https://doi.org/10.1007/BF00505694

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