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Reaction of 5-chloroanthra[1,9-cd]-6-isoxazolone with pyridine bases

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

In the reaction of 5-chloroanthra[1,9-cd]-6-isoxazolone with pyridine bases the chlorine atom is substituted to give the corresponding pyridinium salts. The pyridine ring of the synthesized anthra[1,9-cd]isoxazol-6-one-5-pyridinium chloride was cleaved by the Zincke method. The reduction of the cleavage product, viz., N-(anthra[1′,9′-cd]isoxazol-6-on-5-yl)-5-amino-2,4-pentadienal, under various conditions was investigated.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1186–1188, September, 1981.

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Gornostaev, L.M., Zolotareva, G.I. & Verkhovodova, D.S. Reaction of 5-chloroanthra[1,9-cd]-6-isoxazolone with pyridine bases. Chem Heterocycl Compd 17, 879–882 (1981). https://doi.org/10.1007/BF00505588

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  • DOI: https://doi.org/10.1007/BF00505588

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