Synthesis and thermal decomposition of haloalkoxy-sym-triazines. 6. Synthesis and thermolysis of 2-(2-chloroethoxy)-4-N-methyl-N-cyanoamino-6-dialkylamino-syn-triazines
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2-(2-Chloroethoxy)-4-N-methyl-N-cyanoamino-6-dialkylamino-sym-triazines were synthesized. It was established that thermolysis of the indicated compounds in xylene is accompanied by dechloroalkylation; however, it takes place at the site of both the dialkylamino and alkylcyanoamino groups to give a mixture of two imidazo-sym-triazines. The structures of the latter were confirmed by data from the IR, PMR, and mass spectra.
KeywordsMass Spectrum Organic Chemistry Thermal Decomposition Xylene Thermolysis
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