Chemistry of Heterocyclic Compounds

, Volume 16, Issue 11, pp 1128–1133 | Cite as

Aziridinyl ketones and their heteroanalogs. 5. Synthesis and structures of 2-aryl-3-aroylaziridines

  • V. D. Orlov
  • F. G. Yaremenko
  • V. F. Lavrushin


A number of trans- and cis-isomeric 1-R-2-aryl-3-aroylaziridines were synthesized, and their IR spectra were studied. Intramolecular hydrogen bonding is realized in the trans isomers when R = H, and they exist in the only possible conformation (intermediate between a gauche and a cisoid conformation). cis-Isomers II (R = alkyl) exist in solutions in the form of two conformers, viz., gauche and cisoid conformers, and the gauche conformer is thermodynamically preferable.


Hydrogen Hydrogen Bonding Organic Chemistry Ketone Intramolecular Hydrogen Bonding 
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Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • V. D. Orlov
    • 1
  • F. G. Yaremenko
    • 1
  • V. F. Lavrushin
    • 1
  1. 1.A. M. Gor'kii Kharkov State UniversityKharkov

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