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Chemistry of Heterocyclic Compounds

, Volume 16, Issue 11, pp 1128–1133 | Cite as

Aziridinyl ketones and their heteroanalogs. 5. Synthesis and structures of 2-aryl-3-aroylaziridines

  • V. D. Orlov
  • F. G. Yaremenko
  • V. F. Lavrushin
Article
  • 36 Downloads

Abstract

A number of trans- and cis-isomeric 1-R-2-aryl-3-aroylaziridines were synthesized, and their IR spectra were studied. Intramolecular hydrogen bonding is realized in the trans isomers when R = H, and they exist in the only possible conformation (intermediate between a gauche and a cisoid conformation). cis-Isomers II (R = alkyl) exist in solutions in the form of two conformers, viz., gauche and cisoid conformers, and the gauche conformer is thermodynamically preferable.

Keywords

Hydrogen Hydrogen Bonding Organic Chemistry Ketone Intramolecular Hydrogen Bonding 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • V. D. Orlov
    • 1
  • F. G. Yaremenko
    • 1
  • V. F. Lavrushin
    • 1
  1. 1.A. M. Gor'kii Kharkov State UniversityKharkov

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