Advertisement

Chemistry of Heterocyclic Compounds

, Volume 16, Issue 11, pp 1122–1124 | Cite as

Hydrolysis of carbamates and carbonates of 3-hydroxythiolane 1,1-dioxide

  • P. I. Parkhomenko
  • M. V. Rybakova
  • T. É. Bezmenova
  • T. D. Zaika
Article
  • 83 Downloads

Abstract

Alkylcarbamates of 3-hydroxy-thiolane 1,1-dioxide are hydrolyzed in the presence of bases to give alkyl(1,1-dioxo-3-thiolanyl) amines and 2-thiolene 1,1-dioxide (I). Aryl esters undergo hydrolysis to give sulfone I and 3-hydroxythiolane 1,1-dioxide (II). The corresponding alkyl- and arylcarbonates also form sulfone I and a very small amount of hydroxy derivative II under these conditions.

Keywords

Ester Hydrolysis Sulfone Organic Chemistry Carbamate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    A. Williams, J. Chem. Soc., Perkin Trans. II, No. 6, 808 (1972).Google Scholar
  2. 2.
    A. Williams, J. Chem. Soc., Perkin Trans. II, No. 9, 1244 (1972).Google Scholar
  3. 3.
    T. É. Bezmenova and P. G. Dul'nev, Dokl. Akad. Nauk UKR. SSR, 34, 45 (1972).Google Scholar
  4. 4.
    T. É. Bezmenova, T. S. Lutsii, A. F. Rekashova, and Yu. N. Usenko, Khim. Geterotsikl. Soedin., No. 8, 1060 (1975).Google Scholar
  5. 5.
    L. K. Brice, W. M. Chang, and J. E. Smith, J. Phys. Chem., 71 2814 (1967).Google Scholar
  6. 6.
    L. W. Dittert and T. Higuchi, J. Pharm. Sci., 52, 852 (1963).Google Scholar
  7. 7.
    T. É. Bezmenova, V. P. Tantsyura, R. A. Dorofeeva, and T. S. Lutsii, Khim. Geterotsikl. Soedin., No. 9, 1188 (1976).Google Scholar

Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • P. I. Parkhomenko
    • 1
  • M. V. Rybakova
    • 1
  • T. É. Bezmenova
    • 1
  • T. D. Zaika
    • 1
  1. 1.Petrochemical Sector, Institute of Physical-Organic Chemistry and Coal ChemistryAcademy of Sciences of the Ukrainian SSRKiev

Personalised recommendations