Abstract
The optimum conditions for the hydrogenation of 2,3-dihydropyran to tetrahydropyran on an industrial nickel-chromium catalyst under flow and periodic conditions were found. A regression model for the process was found. The results of hydrogenation of 2,3-dihydropyran by means of a flow reactor and an autoclave of the Vishnevskii type are compared.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
T. E. Nalesnik and N. L. Holy, J. Org. Chem., 42, 372 (1977).
J. Egyed, P. Demerseman, and R. Royer, Bull. Soc. Chim. France, No. 11, Part 2, 3014 (1973).
V. J. Traynelis, W. L. Hergenrother, H. T. Hanson, and J. A. Valicenti, J. Org. Chem., 29, 123 (1964).
P. Picard, D. Leclerq, and J. Moulines, Tetrahedron Lett., No. 32, 2731 (1975).
M. Bartok and A. Molnar, Acta Chim. Hung., 78, 305 (1973).
D. Barbry, B. Hasiak, and C. Glcet, C.R. Acad. Sci., 281, 889 (1975).
A. Weickmann and H. Spänig, French Patent No. 1165673; Chem. Abstr., 54, 19731 (1960).
D. W. Andrus and J. R. Johnson, in: Organic Syntheses, Vol. 23 (1943), p. 90.
R. Paul, Bull. Soc. Chim. France, 53, 1489 (1933); Chem. Abstr., 28, 4056 (1934).
N. S. Smirnova, L. I. Lelyukh, S. N. Chalaya, K. M. Korshunova, and L. G. Chichenkova, in: Research on the Synthesis and Catalysis of Organic Compounds [in Russian], Collective Vol. 5, Saratov (1975), p. 17; Ref. Zh. Khim., 16Zh237 (1975).
A. A. Ponomarev, Syntheses and Reactions of Furan Substances [in Russian], Izd. Saratovsk. Univ., Saratov (1960), p. 202.
C. H. Kline and J. Turkevich, J. Am. Chem. Soc., 67, 498 (1945).
L. E. Schniep and H. H. Geller, J. Am. Chem. Soc., 68, 1646 (1946).
P. A. Moshkin, in: Problems in the Utilization of Pentosan-Containing Raw Material [in Russian], Izd. Akad. Nauk Latv. SSR, Riga (1958), p. 225.
A. A. Strepikheva and F. M. Mandrosova, in: Problems in the Utilization of Pentosan-Containing Raw Material [in Russian], Izd. Akad. Nauk Latv. SSR, Riga (1958), p. 281.
D. G. Manly, U.S. Patent No. 3021342; Chem. Abstr., 56, 15489 (1962).
A. A. Avots, V. S. Aizbalts, I. Ya. Lazdin'sh, and V. A. Kuplenieks, Summaries of Papers Presented at the 3rd All-Union Symposium on Heterogeneous Catalysis in the Chemistry of Heterocyclic Compounds [in Russian], Zinatne, Riga (1981).
K. Hartman (editor), Experiment Planning in the Investigation of Technological Processes [Russian translation], Mir, Moscow (1977), p. 552.
Author information
Authors and Affiliations
Additional information
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 469–472, April, 1982.
Rights and permissions
About this article
Cite this article
Kuplenieks, V.A., Kreile, D.R., Slavinskaya, V.A. et al. Hydrogenation of 2,3-dihydropyran to tetrahydropyran. Chem Heterocycl Compd 18, 351–354 (1982). https://doi.org/10.1007/BF00503549
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00503549