Abstract
The reaction of 2-methylene3-oxoquinuclidine with ketones, β-diketones, keto esters, and cyano esters was studied. Products of mono- and diaddition of the unsaturated ketone are formed in the presence of catalytic or equimolar amounts of sodium ethoxide, as well as without a catalyst (in the case of β-keto esters and β-diketones).
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V. Ya. Vorob'eva, V. A. Bondarenko, E. E. Mikhlina, K. F. Turchin, L. F. Linberg, and L. N. Yakhontov, Khim. Geterotsikl. Soedin., No. 10, 1370 (1977).
V. A. Bondarenko, E. E. Mikhlina, T. Ya. Filipenko, K. F. Turchin, Yu. N. Sheinker, and L. N. Yakhontov, Khim. Geterotsikl. Soedin., No. 3, 371 (1978).
V. A. Bondarenko, E. E. Mikhlina, T. Ya. Filipenko, K. F. Turchin, Yu. N. Sheinker, and L. N. Yakhontov, Khim. Geterotsikl. Soedin., No. 10, 1393 (1979).
A. Fischer, E. Oppenheimer, and S. Cjehn, Tetrahedron, 31, 317 (1975).
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1387–1391, October, 1981.
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Bondarenko, V.A., Mikhlina, E.E., Filipenko, T.Y. et al. Reactions of 2-methylene-3-oxoquinuclidine with carbonyl compounds. Chem Heterocycl Compd 17, 1042–1046 (1981). https://doi.org/10.1007/BF00503538
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DOI: https://doi.org/10.1007/BF00503538