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Synthesis of pyridine and quinoline derivatives of ferrocene from β-chloro-β-ferrocenylacrolein

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

2-Ferrocenylquinolines that contain a hydroxy or methoxy group in the 7 position were obtained by the reaction of β-chloro-β-ferrocenylacrolein with m-anisidine and with m-aminophenol. The introduction of aniline in this reaction leads to the formation of β-ferrocenyl-β-phenylaminoacrolein anil hydrochloride, which cannot be converted to 2-ferrocenylquinoline. 2,3,6-Trisubstituted pyridines that contain a ferrocenyl substituent in the 6 position were obtained by condensation of β-chloro-β-ferrocenylacrolein with β-dicarbonyl compounds.

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Deceased.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1376–1378, October, 1981.

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Krasnikov, V.V., Dorofeenko, G.N. Synthesis of pyridine and quinoline derivatives of ferrocene from β-chloro-β-ferrocenylacrolein. Chem Heterocycl Compd 17, 1032–1034 (1981). https://doi.org/10.1007/BF00503535

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  • DOI: https://doi.org/10.1007/BF00503535

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