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Synthesis of new electron-donor compounds: Bis(2-thia-1,3-propylenedithio)teterathiafulvalene and bis(2-oxo-1,3-propylenedithio)tetrathiafulvalene

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

1,3-Dithiole-2-thione derivatives, which are starting compounds for the synthesis of new electron donors of the tetrathiafulvalene class, viz., bis(2-thia-1,3-propylendithio)tetrathiafulvalene and bis(2-oxo-1,3-propylendithio)tetrathiafulvalene, were obtained by the reaction of bis(tetraalkylamonium) bis(1,3-dithiole-2-thione-4,5-dithiolato)zincates with 1,3-dichlorodimethyl sulfide and 1,3- dibromoacetone.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 471–474, April, 1990.

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Russkikh, V.S., Abashev, G.G. Synthesis of new electron-donor compounds: Bis(2-thia-1,3-propylenedithio)teterathiafulvalene and bis(2-oxo-1,3-propylenedithio)tetrathiafulvalene. Chem Heterocycl Compd 26, 403–406 (1990). https://doi.org/10.1007/BF00497209

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  • DOI: https://doi.org/10.1007/BF00497209

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