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Synthesis and properties of metal collecting phases with silica immobilized 8-Hydroxyquinoline

Synthese und Erprobung einer Metallsammelphase mit auf Kieselgel immobilisiertem 8-Hydroxychinolin

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Zusammenfassung

Eine einfache Methode zur Herstellung von an Kieselgelen immobilisiertem 8-Hydroxychinolin wird beschrieben. Das erhaltene Material wird hinsichtlich seiner Affinität für Kupfer, Nickel, Cobalt, Eisen (III), Mangan(II), Chrom(III), Zink, Cadmium, Blei und Quecksilber(II) untersucht. Die Metallkapazitäten liegen in der Größenordnung von 0,2–0,7 mmol/g, die Verteilungskoeffizienten in der Größenordnung 1000–>90000.

Summary

A simple method for the preparation of silica immobilized 8-hydroxyquinoline is described. The resulting material is investigated for its affinity to copper, nickel, cobalt, iron(III), manganese(II), chromium(III), zinc, cadmium, lead and mercury(II). The metal uptake capacities were found in the range from 0.2 to 0.7 mmol/g, the distribution ratios in the range from 1000 up to > 90000.

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Authors and Affiliations

  1. Fachbereich Chemie und Chemietechnik, Angewandte Chemie, Universität-GHS Paderborn, Warburger Straße 100, D-4790, Paderborn, Germany

    M. Lührmann, N. Stelter & A. Kettrup

Authors
  1. M. Lührmann
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  2. N. Stelter
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  3. A. Kettrup
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Lührmann, M., Stelter, N. & Kettrup, A. Synthesis and properties of metal collecting phases with silica immobilized 8-Hydroxyquinoline. Z. Anal. Chem. 322, 47–52 (1985). https://doi.org/10.1007/BF00493041

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  • DOI: https://doi.org/10.1007/BF00493041

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