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Indole derivatives

LXXVII. Synthesis of 5-arylazoindoles

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Depending on the pH, 1-(1-indolinyl)-3-aryltriazenes (I) or 5-arylazoindolines (II) are formed in the reaction of indoline with aryldiazonium salts. In acid media, I are rearranged to II. The dehydrogenation of I or II with chloranil gives 5-arylazoindoles.

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Literature cited

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See [1] for communication LXXVI.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 648–651, May, 1972.

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Avramenko, V.G., Sarma, P.K. & Suvorov, N.N. Indole derivatives. Chem Heterocycl Compd 8, 587–589 (1972). https://doi.org/10.1007/BF00488151

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  • DOI: https://doi.org/10.1007/BF00488151

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