Abstract
1,4,9-Trioxa-5,5-dichlorospiro[4,5]-7-decene and 1,4,9-trioxa-6-methyl-5,5-dichlorospiro-[4,5]-7-decene were synthesized by condensation of 2-dichloromethylene-1,3-dioxolane with acrolein and crotonic aldehyde.
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Abbreviations
- m:
-
multiplet
- q:
-
quartet
- d:
-
doublet
Literature cited
A. N. Mirskova and A. S. Atavin, in: Chemistry of Acetylenes [in Russian], Nauka, Moscow (1968), p. 7.
A. S. Atavin, A. N. Mirskova, N. N. Chipanina, and R. A. Prelovskaya, Zh. Organ. Khim., 1, 2077 (1965).
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N. Bhacca and D. Williams, Applications of Nuclear Magnetic Resonance in Organic Chemistry [Russian translation], Mir, Moscow (1966), pp. 70, 142.
S. M. McElvain and M. J. Curry, J. Am. Chem. Soc., 70, 3781 (1948).
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 184–185, February, 1974.
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Mirskova, A.N., Proskurina, T.S., Voronov, V.K. et al. 2-Dichloromethylene-1,3-dioxolane in the diels-alder reaction with α,Β- unsaturated aldehydes. Chem Heterocycl Compd 10, 161–162 (1974). https://doi.org/10.1007/BF00487771
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DOI: https://doi.org/10.1007/BF00487771