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Rearrangement of 2,3,5,6-tetrachloro-4-pyridyl β-hydroxyethyl sulfone

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A method for the preparation of 4-mercapto-2,3,5,6-tetrachloropyridine was modified. 2,3,5,6-Tetrachloro-4-pyridyl β-hydroxyethyl sulfone was synthesized and converted to 4-hydroxytetra-chloropyridine by the action of a base. A mechanism for this rearrangement is proposed.

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Literature cited

  1. C. D. S. Tomlin, J. W. Slater, D. Hatley, and C. J. Clayton, British Patent No. 1059990 (1967); Ref. Zh. Khim., 1.0486P (1976).

  2. R. A. Fernandes, H. Heaney, J. M. Jablonski, K. G. Mason, and T. J. Word, J. Chem. Soc., C, 1908 (1969).

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  3. L. S. Sologub, S. D. Moshchitskii, Ya. N. Ivashchenko, and Yu. N. Levchuk, Khim. Geterotsikl. Soedin., No. 2, 514 (1962).

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  4. C. K. Ingold, Theoretical Foundations of Organic Chemistry [Russian translation], Moscow (1973), p. 600.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, 252660, Kiev

    S. D. Moshchitskii, L. S. Sologub, T. V. Kovalevskaya, A. A. Kisilenko & V. P. Kukhar'

Authors
  1. S. D. Moshchitskii
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  2. L. S. Sologub
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  3. T. V. Kovalevskaya
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  4. A. A. Kisilenko
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  5. V. P. Kukhar'
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1642–1645, December, 1978.

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Moshchitskii, S.D., Sologub, L.S., Kovalevskaya, T.V. et al. Rearrangement of 2,3,5,6-tetrachloro-4-pyridyl β-hydroxyethyl sulfone. Chem Heterocycl Compd 14, 1334–1337 (1978). https://doi.org/10.1007/BF00487401

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  • DOI: https://doi.org/10.1007/BF00487401

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