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2,2-Dimethyl-5-(5-R-furfurylidene)-1,3-dioxane-4,6-diones. 3. Selective hydrogenation of the exocyclic double bond and three-dimensional structures of the reaction products

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of 2,2-dimethyl-5-(5-R-furfurylidene)-1,3-dioxane-4,6-diones with sodium borohydride in alcohol leads exclusively to products of hydrogenation of the exocyclic double bond. The three-dimensional structure of one of them — 2,2-dimethyl-5-(5-methyl-furfuryl)-1,3-dioxane-4,6-dioxane — was investigated by x-ray diffraction analysis (XDA).

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Authors and Affiliations

  1. Krasnodar Polytechnical Institute, 350670, Krasnodar

    G. D. Krapivin, V. E. Zavodnik, N. I. Val'ter, V. K. Bel'skii & V. G. Kul'nevich

  2. L. Ya. Karpov Scientific-Research Institute of Phyhsical Chemistry, 107120, Moscow

    G. D. Krapivin, V. E. Zavodnik, N. I. Val'ter, V. K. Bel'skii & V. G. Kul'nevich

Authors
  1. G. D. Krapivin
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  2. V. E. Zavodnik
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  3. N. I. Val'ter
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  4. V. K. Bel'skii
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  5. V. G. Kul'nevich
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Additional information

See [1] for Communication 2.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1201–1207, September, 1989.

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Krapivin, G.D., Zavodnik, V.E., Val'ter, N.I. et al. 2,2-Dimethyl-5-(5-R-furfurylidene)-1,3-dioxane-4,6-diones. 3. Selective hydrogenation of the exocyclic double bond and three-dimensional structures of the reaction products. Chem Heterocycl Compd 25, 1005–1011 (1989). https://doi.org/10.1007/BF00487297

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  • DOI: https://doi.org/10.1007/BF00487297

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