Abstract
It is shown that the addition of aniline proceeds at the carbon-carbon double bond of N-acryloyl-, N-chloroacryloyl-, and N-methylacryloylbenzoxazolones. The basicity of the amine has a substantial effect on the course of the reaction with various amines. Transamidation of the acryloyl residue occurs with strongly basic amines.
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N. A. Aliev and N. N. Mel'nikov, in: Chemical Agents for the Protection of Plants [in Russian], Vol. 4, Moscow (1973), p. 61.
V. Kalcheva and D. Simov, Khim. Geterotsikl. Soedin., 1333 (1971).
S. D. Danilov, Author's Abstract of Master's Dissertation, Moscow (1973).
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1044–1048, August, 1974.
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Aliev, N.A., Razakov, R., Abdullaev, N.D. et al. Reaction of some amines with unsaturated N-acylbenzoxazolones. Chem Heterocycl Compd 10, 909–912 (1974). https://doi.org/10.1007/BF00487107
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DOI: https://doi.org/10.1007/BF00487107