Abstract
Reaction of 2-acetyl-substituted thiophenes and furans with alkyl nitrites in the presence of the corresponding aliphatic alcohols and hydrochloric acid leads to the formation of linear acetals of thienyl- and furylglyoxals, whose structure was established by IR, UV, NMR spectroscopy, and mass spectrometry methods. The main paths of the dissociation of the molecules under electron impact were established.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 772–775, June, 1987.
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Gordeeva, G.N., Kalashnikov, S.M., Popov, Y.N. et al. gem-Dialkoxylation of 2-acetylthiophenes and 2-acetylfurans. Chem Heterocycl Compd 23, 638–641 (1987). https://doi.org/10.1007/BF00486908
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DOI: https://doi.org/10.1007/BF00486908