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Chemistry of Heterocyclic Compounds

, Volume 4, Issue 4, pp 474–476 | Cite as

The chemistry of selenophene

LX. The direction of enolization in β-diketones of the selenophene series with a 3-selenienyl radical
  • Yu. K. Yur'ev
  • N. N. Magdesieva
  • A. T. Monakhova
Article
  • 73 Downloads

Abstract

In the present work it has been shown that 3-(2-selenenoylacetyl)-selenophene is enolized at the carboxyl group adjacent to the 2-selenienyl radical and 3-(benzoylacetyl)selenophene at the carboxyl group adjacent to the phenyl radical (judging from the formation of the corresponding isoxazoles by the reaction of these diketones with hydroxylamine). On reduction with lithium aluminum hydride, methyl 3-selenophenecarboxylate has given 3-selenienylmethanol and the nitrile of the same acid has yielded 3-selenophenealdehyde. Several new chalcones and isoxazoles with β-selenienyl radicals have been described.

Keywords

Aluminum Methyl Lithium Organic Chemistry Carboxyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau 1971

Authors and Affiliations

  • Yu. K. Yur'ev
    • 1
  • N. N. Magdesieva
    • 1
  • A. T. Monakhova
    • 1
  1. 1.Lomonosov Moscow State UniversityUSSR

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