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Chemistry of Heterocyclic Compounds

, Volume 4, Issue 4, pp 459–461 | Cite as

Syntheses of di- and tetrahydropyrroles

III. Reaction of methyl α-methoxycarbonyl-β, β-dimethyl-γ-nitrobutyrate with methyl acrylate under the conditions of the Michael reaction
  • B. M. Sheiman
  • V. B. Spiro
  • N. B. Chernysheva
  • L. M. Shmuilovich
  • I. M. Kustanovich
  • V. N. Berezovskii
Article
  • 26 Downloads

Abstract

Methyl α-methoxycarbonyl-β, β-dimethyl-γ-nitrobutyrate adds to methyl acrylate by the Michael's reaction at its γ-carbon atom, in contrast to ethyl α-acetyl-β, β-dimethyl-γ-nitrobutyrate which, in the analogous reaction, adds at the α-carbon atom. The structure of the compounds obtained has been established on the basis of their NMR spectra.

Keywords

Methyl Ethyl Organic Chemistry Acrylate Methyl Acrylate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau 1971

Authors and Affiliations

  • B. M. Sheiman
    • 1
  • V. B. Spiro
    • 1
  • N. B. Chernysheva
    • 1
  • L. M. Shmuilovich
    • 1
  • I. M. Kustanovich
    • 1
  • V. N. Berezovskii
    • 1
  1. 1.All-Union Scientific-Research Vitamin InstituteMoscow

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