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Chemistry of Heterocyclic Compounds

, Volume 4, Issue 4, pp 452–456 | Cite as

Alkoxy compounds

XXIII. Synthesis, properties, PMR spectra, and stereochemistry of 2-alkyl-2-alkoxymethyl-1, 3-propanediols and 2, 2, 5-trialkyl-5-alkoxymethyl-1,3-dioxanes
  • Yu. Yu. Samitov
  • G. I. Goryashina
  • A. V. Bogatskii
  • O. S. Stepanova
Article
  • 28 Downloads

Abstract

The reduction of alkoxymethylalkylmalonic esters with lithium aluminum hydride has given previously unknown 2-alkyl-2-alkoxymethyl-1, 3-propanediols, and by the condensation of these with ketones six previously unreported 2, 2, 5-trialkyl-5-alkoxymethyl-1, 3-dioxanes have been synthesized. The PMR spectra of these compounds have been studied and the unsymmetrical boat conformation has been shown for the 2, 2, 5-trialkyl-5-alkoxymethyl-1, 3-dioxanes. The causes of the stereochemical features of the compounds mentioned are discussed.

Keywords

Aluminum Ester Lithium Organic Chemistry Ketone 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau 1971

Authors and Affiliations

  • Yu. Yu. Samitov
    • 1
    • 2
  • G. I. Goryashina
    • 1
    • 2
  • A. V. Bogatskii
    • 1
    • 2
  • O. S. Stepanova
    • 1
    • 2
  1. 1.Mechnikov Odessa State UniversityUSSR
  2. 2.Ul'yanova-Lenin Kazan State UniversityUSSR

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