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Alkoxy compounds

XXII. Synthesis and PMR spectra of some 2-substituted 5-alkyl-5-α-alkoxyethyl-1,3-dioxanes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Six 2, 2, 5-trialkyl-5-α-alkoxyethyl-1, 3-dioxanes have been synthesized for the first time by the condensation of 2-alkyl-2-α-alkoxyethyl-1, 3-propane diols with ketones, and it has been shown by a study of their PMR spectra that they exist in the unsymmetrical boat conformation. The PMR spectra of a number of previously-synthesized 2-alkyl(aryl)-5-alkyl-5-α-alkoxyethyl-1, 3-dioxanes have been considered and it has been shown that from an analysis of the spectra it is possible to estimate the contents of geometrical isomers in a mixture. The stereochemistry of these compounds has been discussed.

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Authors and Affiliations

  1. Mechnikov Odessa State University, USSR

    Yu. Yu. Samitov, N. L. Garkovik, A. V. Bogatskii & S. A. Zolotareva

  2. Ul'yanova-Lenin Kazan State University, USSR

    Yu. Yu. Samitov, N. L. Garkovik, A. V. Bogatskii & S. A. Zolotareva

Authors
  1. Yu. Yu. Samitov
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  2. N. L. Garkovik
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  3. A. V. Bogatskii
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  4. S. A. Zolotareva
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Additional information

For part XXI, see [10].

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Samitov, Y.Y., Garkovik, N.L., Bogatskii, A.V. et al. Alkoxy compounds. Chem Heterocycl Compd 4, 448–451 (1971). https://doi.org/10.1007/BF00486753

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  • DOI: https://doi.org/10.1007/BF00486753

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