Abstract
The reaction of furfural and its homologs with vinyl and ethyl ethers of o-, m-, and p-aminophenols at room temperature without the addition of any catalyst whatever leads to the amine-aldehyde condensation with the formation of the corresponding ethers of furfurylidene-aminophenols. The structure of the latter has been shown by hydrolysis, hydrogenation, and independent synthesis.
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References
R. Ehrhardt, Ber., 30, 2014, 1897.
V. I. Isagulyants and G. M. Egorova, The Chemistry of Petroleum [in Russian], Gostoptekhizdat, 1949.
H. Schiff, Lieb. Ann., 201, 355, 1880.
W. König, J. pr. Chem., (2) 88, 193, 1913.
J. Stenhouse, Lieb. Ann., 156, 197, 1870.
H. Schiff, Lieb. Ann., 239, 349, 1887.
K. Nakanishi, Infrared Spectra. Practical [Russian translation], Mir, Moscow, p. 45, 1965.
Khorana, Chem. Rev., 53, 145, 1953.
M. F. Shostakovskii, G. G. Skvortsova, and M. Ya. Samoilova, ZhOKh, 31, 3226, 1961.
V. J. Fraynelis, J. J. Miskel, and J. R. Sowa, J. Org. Chem., 22, 1269, 1957.
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Skvortsova, G.G., Garashchenko, Z.M., An, V.V. et al. Synthesis of vinyl ethers of furfurylideneaminophenols. Chem Heterocycl Compd 4, 432–434 (1971). https://doi.org/10.1007/BF00486748
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DOI: https://doi.org/10.1007/BF00486748