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Recyclization of 4-oxo-1,3-benzothiazinium salts. Synthesis of o-mercaptophenyl-1,2,4-triazoles and metal chelates based on them

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A method based on the reaction of 4-oxo-1,3-benzothiazinium perchlorates with hydrazines is developed for synthesizing 5-(o-mercaptophenyl)-1,2,4-triazoles. Their complexes with Ni(II), Co(II), and Zn(II) are prepared. The o-mercaptophenyltriazoles are capable of undergoing oxidative dimerization to give disulfides.

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Authors and Affiliations

  1. Scientific-Research Institute of Physical and Organic Chemistry, Rostov State University, 344090, Rostov-on-Don

    Yu. I. Ryabukhin, O. B. Korzhavina, A. D. Garnovskii, A. P. Knyazev & P. B. Terent'ev

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  1. Yu. I. Ryabukhin
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  2. O. B. Korzhavina
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  3. A. D. Garnovskii
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  4. A. P. Knyazev
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  5. P. B. Terent'ev
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1220–1226, September, 1991.

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Ryabukhin, Y.I., Korzhavina, O.B., Garnovskii, A.D. et al. Recyclization of 4-oxo-1,3-benzothiazinium salts. Synthesis of o-mercaptophenyl-1,2,4-triazoles and metal chelates based on them. Chem Heterocycl Compd 27, 981–986 (1991). https://doi.org/10.1007/BF00484362

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  • DOI: https://doi.org/10.1007/BF00484362

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