Chemistry of Heterocyclic Compounds

, Volume 25, Issue 5, pp 555–558 | Cite as

Polyfluorinated nitrile oxides

  • N. V. Vasil'ev
  • V. S. Savostin
  • A. F. Kolomiets
  • G. A. Sokol'skii


(2+3)-Cycloaddition of polyfluorinated aliphatic nitrile oxides, generated in situ, to donor dipolarophiles takes place regioselectively to give the 5-substituted isoxazolines, and is limited by the donor and steric properties of the dipolarophiles.


Oxide Organic Chemistry Nitrile Isoxazolines Nitrile Oxide 
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Literature Cited

  1. 1.
    N. D. Del'tsova, É. S. Ananyan, and N. P. Gambaryan, Izv. Akad. Nauk SSSR, Ser. Khim., No. 2, 362 (1971).Google Scholar
  2. 2.
    W. J. Middleton, J. Fluor. Chem., 22, 418 (1983).Google Scholar
  3. 3.
    W. J. Middleton, J. Org. Chem., 49, 919 (1984).Google Scholar
  4. 4.
    N. V. Vasil'ev, A. F. Kolomiets, and G. A. Sokol'skii, Zh. Org. Khim., 16, 2233 (1980).Google Scholar
  5. 5.
    B. J. Wakefield and D. J. Wright, J. Chem. Soc., C., No. 2, 116 (1970).Google Scholar
  6. 6.
    C. Grundman and P. Grünanger, The Nitrile Oxides, Springer-Verlag, Berlin (1971).Google Scholar
  7. 7.
    N. V. Vasil'ev, A. G. Kolomiets, and G. A. Sokol'skii, Zh. Vses, Khim. Ob-vo, 26, 350 (1981).Google Scholar
  8. 8.
    B. L. Dyatkin, A. A. Gevorkyan, and I. L. Knunyants, Zh. Org. Khim., 36, 1326 (1966).Google Scholar

Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • N. V. Vasil'ev
  • V. S. Savostin
  • A. F. Kolomiets
  • G. A. Sokol'skii

There are no affiliations available

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