Chemistry of Heterocyclic Compounds

, Volume 25, Issue 5, pp 553–555 | Cite as

Synthesis of 15- and 18-membered polythiamacrocylic ligands

  • V. V. Pavlishchuk
  • P. E. Strizhak


Reaction of 1,8-dimercapto-3,6-dithioactane with oxa-, aza-, and thiadihaloderivatives under high dilution conditions in the presence of cesium carbonate, which acts as a template for the condensation reaction, produces 15- and 18-membered polythiamacrocyclic ligands in yields greater than 50%.


Organic Chemistry Cesium Condensation Reaction High Dilution Dilution Condition 
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Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • V. V. Pavlishchuk
    • 1
  • P. E. Strizhak
    • 1
  1. 1.L. V. Pisarzhevskii Institute of Physical ChemistryAcademy of Sciences of the Ukrainian SSRKiev

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