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Chemistry of Heterocyclic Compounds

, Volume 25, Issue 5, pp 553–555 | Cite as

Synthesis of 15- and 18-membered polythiamacrocylic ligands

  • V. V. Pavlishchuk
  • P. E. Strizhak
Article

Abstract

Reaction of 1,8-dimercapto-3,6-dithioactane with oxa-, aza-, and thiadihaloderivatives under high dilution conditions in the presence of cesium carbonate, which acts as a template for the condensation reaction, produces 15- and 18-membered polythiamacrocyclic ligands in yields greater than 50%.

Keywords

Organic Chemistry Cesium Condensation Reaction High Dilution Dilution Condition 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • V. V. Pavlishchuk
    • 1
  • P. E. Strizhak
    • 1
  1. 1.L. V. Pisarzhevskii Institute of Physical ChemistryAcademy of Sciences of the Ukrainian SSRKiev

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