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Chemistry of Heterocyclic Compounds

, Volume 25, Issue 5, pp 516–521 | Cite as

Synthesis and properties of 2,7-diazabicyclo[2.2.2]octane-3,8-diones and -3,8-dithiones

  • Z. A. Kalme
  • É. É. Liepin'sh
  • Yu. É. Pelcher
  • G. Yu. Dubur
Article
  • 34 Downloads

Abstract

In an alkaline medium, 3,4-dihydropyridin-2(1H)-ones form 2,7-diazebicyclo[2.2.2]-octane-3,8-diones, which are thiolated to the corresponding dithiones. The alkylation of the last proceeds at the sulfur atoms with the formation of 2,7-diazabicyclo[2.2.2]octa-2,7-dienes.

Keywords

Sulfur Organic Chemistry Diene Alkylation Diones 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • Z. A. Kalme
    • 1
  • É. É. Liepin'sh
    • 1
  • Yu. É. Pelcher
    • 1
  • G. Yu. Dubur
    • 1
  1. 1.Institute of Organic SynthesisAcademy of Sciences of the Latvian SSRRiga

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