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Synthesis and properties of 2,7-diazabicyclo[2.2.2]octane-3,8-diones and -3,8-dithiones

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

In an alkaline medium, 3,4-dihydropyridin-2(1H)-ones form 2,7-diazebicyclo[2.2.2]-octane-3,8-diones, which are thiolated to the corresponding dithiones. The alkylation of the last proceeds at the sulfur atoms with the formation of 2,7-diazabicyclo[2.2.2]octa-2,7-dienes.

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Authors and Affiliations

  1. Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga

    Z. A. Kalme, É. É. Liepin'sh, Yu. É. Pelcher & G. Yu. Dubur

Authors
  1. Z. A. Kalme
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  2. É. É. Liepin'sh
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  3. Yu. É. Pelcher
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  4. G. Yu. Dubur
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 620–625, May, 1989.

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Kalme, Z.A., Liepin'sh, É.É., Pelcher, Y.É. et al. Synthesis and properties of 2,7-diazabicyclo[2.2.2]octane-3,8-diones and -3,8-dithiones. Chem Heterocycl Compd 25, 516–521 (1989). https://doi.org/10.1007/BF00482496

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  • DOI: https://doi.org/10.1007/BF00482496

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