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Chemistry of Heterocyclic Compounds

, Volume 25, Issue 5, pp 494–497 | Cite as

Benzenoid-quinoid tautomerism of azomethines and their structural analogs. 43. Phenylmercury derivatives of 3-hydroxy-2-acetyl(benzoyl)benzo[b]thiophene and 3-hydroxy-1-methylindole-2-carbaldehyde imines

  • E. N. Shepelenko
  • A. D. Dubonosov
  • V. A. Bren'
  • L. M. Sitkina
  • A. É. Lyubarskaya
  • V. I. Minkin
Article

Abstract

Phenylmercury derivatives of 3-hydroxy-2-acetyl(benzoyl)benzo[b]thiophene and 3-hydroxy-1-methyl-2-carbaldehyde N-aryl- and N-alkylimines, to which a keto enamine structure with strong intramolecular coordination of the mercury atom and the carbonyl oxygen atom was assigned on the basis of the electronic and vibrational spectra, were synthesized. Compounds of the indole series fluoresce intensely with the usual values of the Stokesian shifts.

Keywords

Oxygen Mercury Organic Chemistry Carbonyl Oxygen Atom 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • E. N. Shepelenko
    • 1
  • A. D. Dubonosov
    • 1
  • V. A. Bren'
    • 1
  • L. M. Sitkina
    • 1
  • A. É. Lyubarskaya
    • 1
  • V. I. Minkin
    • 1
  1. 1.Scientific-Research Institute of Physical and Organic ChemistryM. A. Suslov Rostov State UniversityRostov-on-Don

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