Abstract
The Mannich reaction is used to obtain 2-(β-diethylaminoethyl)-5-vinylpyridine from 2-methyl-5-vinylpyridine. Decomposition of a quaternary salt of 2-(β-diethylaminoethyl)-5-vinylpyridine gives 2, 5-divinylpyridine.
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References
J. E. Mahan, United States patent 2728770, 1955; C. A., 51, 1299, 1957.
Tseou Heou-Feo, Bull. Soc. chim. France, 103, 1935.
H. E. Reich and R. Levine, J. Am. Chem. Soc., 77, 4913, 1955.
A. J. Matuszko and A. Taurins, Canad. J. Chem., 32, 538, 1954.
T. F. Cummings and J. R. Shelton, J. Org. Chem., 25, 419, 1960.
M. I. Farberov and G. S. Mironov, Kinetika i kataliz, 4, 526, 1963.
E. Sh. Kagan and B. I. Ardashev, KhGS (Chemistry of Heterocyclic Compounds], 701, 1967.
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Mezheritskii, V.V., Kagan, E.S. & Ardashev, B.I. Synthesis of 2, 5-divinylpyridine by the mannich reaction. Chem Heterocycl Compd 3, 543 (1967). https://doi.org/10.1007/BF00481599
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DOI: https://doi.org/10.1007/BF00481599