Abstract
The mass spectra of isomeric peracetylated glycosides, substituted in the C(1)-position with thiazolyl and thiazolinylidene thioureido groups, reveal qualitative and quantitative differences in the processes associated with elimination of fragments containing the thioureido functional group. We have studied, in addition to cleavage of the acetoxy groups in the glycosidic units, the fragmentation processes of the carbohydrate unit.
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Communication 1, see [1]
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1539–1543, November, 1989.
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Rashkes, Y.V., Mil'grom, Y.M. & Ambartsumova, R.F. Mass spectrometeric study of thiocarbamoyl-substituted 2-aminothiazoles and 2-iminothiazolines. 2. N-thiazolyl- and N-thiazolinylidene-N′-peracetyl glycosylthioureas. Chem Heterocycl Compd 25, 1289–1293 (1989). https://doi.org/10.1007/BF00481525
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DOI: https://doi.org/10.1007/BF00481525