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Chemistry of polyene and polyyne compounds

XXVII. Behavior of 5-amino-5-methyl-1,3-hexadiyne in addition reactions

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The behavior of 5-amino-5-methyl-l,3-hexadiyne (I) during hydration and during the nucleophilic addition of alcohols and secondary amines was studied. Compound I was used to synthesize 2,2-dimethyl-2,3-dihydro-4-pyridone, 2,5,5-trimethyl-Δ2,3-dihydro-4-pyrrolone, and 4-substituted 2,5,5-trimethyl-Δ1,2,3,4-pyrroles.

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Literature Cited

  1. B. P. Gusev and V. F. Kucherov, Izv. Akad. Nauk SSSR, Ser. Khim., 1318 (1964).

  2. B. P. Gusev, E. A. Él'perina, and V.F. Kucherov, Izv. Akad. Nauk SSSR, Ser. Khim., 2345 (1967).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    B. P. Gusev, E. A. Él'perina & V. F. Kucherov

Authors
  1. B. P. Gusev
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  2. E. A. Él'perina
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  3. V. F. Kucherov
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Additional information

See Izv. Akad. Nauk SSR, Ser. Khim., 141 (1971) for communication XXVI.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1530–1532, November, 1971.

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Gusev, B.P., Él'perina, E.A. & Kucherov, V.F. Chemistry of polyene and polyyne compounds. Chem Heterocycl Compd 7, 1424–1426 (1971). https://doi.org/10.1007/BF00481110

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  • DOI: https://doi.org/10.1007/BF00481110

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