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Chemistry of ethylenimine

II. On the mechanism of the oxidative conversions of N-aminoethylenimine

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The structure of the compounds formed by the oxidative conversions of N-aminoethylenimine (I) was established by the application of IR spectrocopy, PMR, gas-liquid chromatography, and independent syntheses. Basically the reaction proceeds with the formation of ethylideneaminoethylenimine (II); in addition to this, bisaziridine, acetaldazine, and the hydrazone of acetaldehyde are also formed.

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References

  1. L. Odrit and B. Ogg, Hydrazine Chemistry [Russian translation], Moscow, 1954.

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  3. R. Reed, Hydrazine and Derivatives. Res. Inst. Publ., London, 5, 1957.

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  4. S. A. Hiller, A. V. Eremeev, M. Yu. Ludak, and V. A. Pestunovich, KhGS. [Chemistry of Heterocyclic Compounds], 815, 1968.

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Authors and Affiliations

  1. Institute of Organic Synthesis AS LatvSSR, Riga

    S. A. Hiller, A. V. Eremeev, M. Yu. Lidak & V. A. Pestunovich

Authors
  1. S. A. Hiller
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  2. A. V. Eremeev
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  3. M. Yu. Lidak
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  4. V. A. Pestunovich
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Hiller, S.A., Eremeev, A.V., Lidak, M.Y. et al. Chemistry of ethylenimine. Chem Heterocycl Compd 4, 592–594 (1971). https://doi.org/10.1007/BF00481025

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  • DOI: https://doi.org/10.1007/BF00481025

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