Skip to main content
SpringerLink
Log in

Synthesis and some reactions of sulfides of the thiophene series

XVI. The direction of the dealkylation of α,β-bis(alkylthio)thiophenes with sodium in liquid ammonia

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The action of two equivalents of sodium in liquid ammonia on bis(alkylthio)thiophenes of types Ia and b leads to the splitting off of the alkyl group from the sulfur atom in the α-position of the thiophene ring and the formation of the corresponding α-mercaptothiophenes II and III. The PMR spectra of the compounds obtained are given.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Ya. L. Gol'dfarb and M. A. Kalik, KhGS [Chemistry of Heterocyclic Compounds], 4, 788, 1968.

    Google Scholar 

  2. W. E. Truce, D. P. Tate, and D. N. Burge, J. Am. Chem. Soc. 82, 2872, 1960.

    Google Scholar 

  3. W. E. Truce and J. J. Breiter, J. Am. Chem. Soc., 84, 1621, 1962.

    Google Scholar 

  4. T. Wallace and F. A. Baron, J. Org. Chem., 30, 3520, 1965.

    Google Scholar 

  5. A. N. Lyubimov, A. V. Varenik, and A. V. Kessenikh, ZhSKh, 7, 694, 1966.

    Google Scholar 

  6. S. Gronowitz and R. A. Hoffman, Ark. kemi, 16, 501, 515, 539, 560, 1960.

    Google Scholar 

  7. N. M. Sergeev, Thesis [in Russian], Kazan, 1966.

  8. J. Pople, W. Schneider, and H. Bernstein, High Resolution Nuclear Magnetic Resonance [Russian translation], IL, Ch. 6, 1962.

  9. S. Gronowitz, Ark. kemi, 13, 269, 1958.

    Google Scholar 

  10. Ya. L. Gol'dfarb and Yu. B. Vol'kenshtein, DAN, 128, 536, 1959.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Zelinskii Institute of Organic Chemistry AS USSR, Moscow

    V. S. Bogdanov, M. A. Kalik, A. V. Kessenikh & Ya. L. Gol'dfarb

Authors
  1. V. S. Bogdanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. A. Kalik
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Kessenikh
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ya. L. Gol'dfarb
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

For part XV, see [1].

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bogdanov, V.S., Kalik, M.A., Kessenikh, A.V. et al. Synthesis and some reactions of sulfides of the thiophene series. Chem Heterocycl Compd 4, 574–578 (1971). https://doi.org/10.1007/BF00481019

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00481019

Keywords

Search

Navigation