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Vinylpyrylation of aromatic compounds

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of β-ethoxyvinylpyrylium salts with aromatic compounds gives styrylpyrylium salts, which are also formed from methylpyrylium salts, ethyl orthoformate, and aromatic compounds. The previously unknown phenomenon of attack by a carbonium cation on the meta position of a benzene ring passivated by a nitro group (nitrobenzene) was detected.

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Literature cited

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 743–745, June, 1974.

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Mezheritskii, V.V., Vasserman, A.L. & Dorofeenko, G.N. Vinylpyrylation of aromatic compounds. Chem Heterocycl Compd 10, 645–646 (1974). https://doi.org/10.1007/BF00480913

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  • DOI: https://doi.org/10.1007/BF00480913

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