Abstract
3,5,7-Tribromo-1-azaadamantane is made by the action of sodium nitrite on 3,5,7-triamino-1-azaadamantane in concentrated hydrobromic acid. The reduction of this compound with hydrazine hydrate in the presence of a nickel catalyst gives 1-azaadamantane.
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For Communication 12, see [1].
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1083–1085, August, 1990.
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Kuznetsov, A.I., Béér, A.M. Heteroadamantanes and their derivatives. 13. Synthesis of 1-azaadamantane and some derivatives of it. Chem Heterocycl Compd 26, 907–908 (1990). https://doi.org/10.1007/BF00480868
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DOI: https://doi.org/10.1007/BF00480868