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Photochemical reactions of 7-aminocoumarins. 7. Reaction of 3-iodo-4-methyl-7-diethylcoumarin with olefins

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A number of new 7-aminocoumarins having an unsaturated substituent in the 3 position were obtained as a result of photolysis of 3-iodo-4-methyl-7-diethylaminocoumarin with olefins, viz., styrene, acrylonitrile, methyl acrylate, methyl methacrylate, 4-vinylpyridine, 2-ethoxypropene, indent, ethyl Β-anilinocrotonate, and 2,5-norbornadiene, as well as with phenylacetylene. Regiospecificity and stereospecificity of the investigated photoreactions were established. The spectral-luminescence characteristics of the synthesized compounds are presented.

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Authors and Affiliations

  1. K. A. Timiryazev Moscow Agricultural Academy, 127550, Moscow

    N. A. Gordeeva, M. A. Kirpichenok, D. S. Yufit, Yu. T. Struchkov & I. I. Grandberg

Authors
  1. N. A. Gordeeva
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  2. M. A. Kirpichenok
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  3. D. S. Yufit
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  4. Yu. T. Struchkov
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  5. I. I. Grandberg
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Additional information

For Communication 6, see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1033–1041, August, 1990.

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Gordeeva, N.A., Kirpichenok, M.A., Yufit, D.S. et al. Photochemical reactions of 7-aminocoumarins. 7. Reaction of 3-iodo-4-methyl-7-diethylcoumarin with olefins. Chem Heterocycl Compd 26, 863–869 (1990). https://doi.org/10.1007/BF00480857

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  • DOI: https://doi.org/10.1007/BF00480857

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