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Proton-transfer reactions in azoles

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The kinetics of proton transfer in solutions of diazoles were investigated by 1H and 13C NMR spectroscopy. The kinetic data are explained by means of quantummechanical representations of the elementary act of proton transfer. It is concluded that proton transfer has substantial collective character. It was established that a small number of coordination centers (transition metal ions) have a dramatic effect on proton transfer owing to extraspheral complexing.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, 117312, Moscow

    V. N. Babin & E. B. Zavelovich

Authors
  1. V. N. Babin
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  2. E. B. Zavelovich
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 781–786, June, 1977.

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Babin, V.N., Zavelovich, E.B. Proton-transfer reactions in azoles. Chem Heterocycl Compd 13, 634–638 (1977). https://doi.org/10.1007/BF00480669

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  • DOI: https://doi.org/10.1007/BF00480669

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