Abstract
2-(Substituted vinyl)-1,3-diazabicyclo[3.1.0]hexanes are formed in the reaction of 2-aminomethylaziridine with some α-unsaturated carbonyl compounds containing a C=C bond in the a position, whereas 2-(substituted ethynyl)-1,3-diazabicyclo[3.1.0]hexanes are formed with α-acetylenic aldehydes. It was established by PMR spectroscopy that the 2-substituted 1,3-diazabicyclo[3.1.0]hexanes are mixtures of endo and exo isomers.
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S. A. Giller, M. Yu. Lidak, A. V. Eremeev, V. A. Kholodnikov, and V. A. Pestunovich, Khim. Geterotsikl. Soedin., No. 5, 607 (1971).
S. A. Giller, M. Yu. Lidak, A. V. Eremeev, and V. A. Kholodnikov, Khim. Geterotsikl. Soedin., No. 4, 483 (1972).
A. V. Eremeev, D. A. Tikhomirov, and é. é. Liepin'sh, Khim. Geterotsikl. Soedin., No. 2, 207 (1977).
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 758–762, June, 1977.
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Eremeev, A.V., Kholodnikov, V.A., Tikhomirov, D.A. et al. Reaction of 2-aminomethylaziridine with α-unsaturated carbonyl compounds. Chem Heterocycl Compd 13, 614–617 (1977). https://doi.org/10.1007/BF00480664
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DOI: https://doi.org/10.1007/BF00480664