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Atranes

XXXIV. Molecular and crystal structure of 1-substituted silatranes and germatranes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The structures of 1-substituted silatranes and germatranes \([XM(\)(M = Si, Ge)] are discussed on the basis of data from x-ray diffraction analysis and other physicochemical methods. The found values of the interatomic distances and valence angles in molecules of these compounds directly prove the existence of a transannular N→M coordinate bond and confirm the correctness of the previously proposed geometrical model of a molecule with a trigonal-bipyramidal orientation of the valence bonds of the central atom M. In metalloatranes (M = Si, Ge, B), the distance from the nitrogen atom to the plane in which the three oxygen atoms lie is a constant value (2.00±0.05 Å). The effect of substituent X on the structure of the molecule was established.

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Authors and Affiliations

  1. Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, Riga

    Ya. Ya. Bleidelis, A. A. Kemme, G. I. Zelchan & M. G. Voronkov

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  1. Ya. Ya. Bleidelis
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  2. A. A. Kemme
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  3. G. I. Zelchan
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  4. M. G. Voronkov
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 617–623, May, 1973.

See [1] for communication XXXIII.

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Bleidelis, Y.Y., Kemme, A.A., Zelchan, G.I. et al. Atranes. Chem Heterocycl Compd 9, 570–575 (1973). https://doi.org/10.1007/BF00480566

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  • DOI: https://doi.org/10.1007/BF00480566

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